EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, ocean acidification, contaminants and litter. The chosen parameters are relevant for the Marine Strategy Framework Directive (MSFD), in particular for descriptors 5, 8, 9 and 10. The datasets contain standardized, harmonized and validated data collections from seafloor litter. Datasets concerning seafloor litter data are loaded in a central database after a semi-automated validation phase. Once loaded, a data assessment is performed in order to check data consistency and potential errors are corrected thanks to a feedback loop with data originators. EMODnet seafloor litter data and database are hosted and maintained by ‘Istituto Nazionale di Oceanografia e di Geofisica Sperimentale, Division of Oceanography (OGS/NODC)’ from Italy. For seafloor litter, the harmonized datasets contain all unrestricted EMODnet Chemistry data on seafloor litter data, including 12438 CDI records. The temporal range covered is from 2006-10-01 to 2018-08-16. Data are formatted following Guidelines and forms for gathering marine litter data, which can be found at: https://www.emodnet-chemistry.eu/documents/projectdocuments. The harmonized datasets can be downloaded as EMODnet Sea-floor litter data format Version 1.0, which is a csv file, tab separated values. The original datasets can be searched and downloaded from EMODnet Chemistry Download Service: https://emodnet-chemistry.maris.nl/search

This gridded product visualizes 1960 - 2014 water body ammonium concentration (umol/l) in the North Sea domain, for each season (winter: December – February; spring: March – May; summer: June – August; autumn: September – November). It is produced as a Diva 4D analysis, version 4.6.9: a reference field of all seasonal data between 1960-2014 was used; results were logit transformed to avoid negative/underestimated values in the interpolated results; error threshold masks L1 (0.3) and L2 (0.5) are included as well as the unmasked field. Every step of the time dimension corresponds to a 10-year moving average for each season. The depth dimension allows visualizing the gridded field at various depths.

This gridded product visualizes 1960 - 2014 water body nitrate concentration (umol/l) in the North Sea domain, for each season (winter: December – February; spring: March – May; summer: June – August; autumn: September – November). It is produced as a Diva 4D analysis, version 4.6.9: a reference field of all seasonal data between 1960-2014 was used; results were logit transformed to avoid negative/underestimated values in the interpolated results; error threshold masks L1 (0.3) and L2 (0.5) are included as well as the unmasked field. Every step of the time dimension corresponds to a 10-year moving average for each season. The depth dimension allows visualizing the gridded field at various depths.

Moving 10-years analysis of Silicate at Northeast Atlantic Ocean for each season. - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December Every year of the time dimension corresponds to the 10-year centred average of each season. Decades span - from 1963-1972 until 2005-2014 (winter) - from 1979-1988 until 2005-2014 (spring) - from 1990-1999 until 2005-2014 (summer) - from 1964-1973 until 2005-2014 (autumn) Observational data span from 1962 to 2014. Depth range (IODE standard depths): -3000.0, -2500.0, -2000.0, -1750, -1500.0, -1400.0, -1300.0, -1200.0, -1100.0, -1000.0, -900.0, -800.0, -700.0, -600.0, -500.0, -400.0, -300.0, -250.0, -200.0, -150.0, -125.0, -100.0, -75.0, -50.0,-40.0, -30.0, -20.0, -10.0, -5.0, -0.0 Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVA analysis: Geostatistical data analysis by DIVA (Data-Interpolating Variational Analysis) tool. GEBCO 1min topography is used for the contouring preparation. Analyzed filed masked using relative error threshold 0.3 and 0.5 DIVA settings. Signal to noise ratio and correlation length were optimized and filtered vertically and a seasonally-averaged profile was used. Logarithmic transformation applied to the data prior to the analysis. Background field: the data mean value is subtracted from the data. Detrending of data: no, Advection consraint applied: no. Units: umol/l

Moving 10-years analysis of Phosphate at Northeast Atlantic Ocean for each season: - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December Every year of the time dimension corresponds to the 10-year centred average of each season. Decades span : - from 1963-1972 until 2005-2014 (winter) - from 1963-1972 until 2005-2014 (spring) - from 1964-1973 until 2005-2014 (summer) - from 1964-1973 until 2005-2014 (autumn) Observational data span from 1962 to 2014. Depth range (IODE standard depths): -3000.0, -2500.0, -2000.0, -1750, -1500.0, -1400.0, -1300.0, -1200.0, -1100.0, -1000.0, -900.0, -800.0, -700.0, -600.0, -500.0, -400.0, -300.0, -250.0, -200.0, -150.0, -125.0, -100.0, -75.0, -50.0,-40.0, -30.0, -20.0, -10.0, -5.0, -0.0 Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVA analysis: Geostatistical data analysis by DIVA (Data-Interpolating Variational Analysis) tool. GEBCO 1min topography is used for the contouring preparation. Analyzed filed masked using relative error threshold 0.3 and 0.5 DIVA settings. Signal to noise ratio and correlation length were optimized and filtered vertically and a seasonally-averaged profile was used. Logarithmic transformation applied to the data prior to the analysis. Background field: the data mean value is subtracted from the data. Detrending of data: no, Advection consraint applied: no. Units: umol/l

This gridded product visualizes 1960 - 2014 water body silicate concentration (umol/l) in the North Sea domain, for each season (winter: December – February; spring: March – May; summer: June – August; autumn: September – November). It is produced as a Diva 4D analysis, version 4.6.9: a reference field of all seasonal data between 1960-2014 was used; results were logit transformed to avoid negative/underestimated values in the interpolated results; error threshold masks L1 (0.3) and L2 (0.5) are included as well as the unmasked field. Every step of the time dimension corresponds to a 10-year moving average for each season. The depth dimension allows visualizing the gridded field at various depths.

Moving 10-years analysis of Oxygen at Northeast Atlantic Ocean for each season: - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December. Every year of the time dimension corresponds to the 10-year centred average of each season. Decades span from 1963-1972 until 2005-2014. Observational data span from 1963 to 2014. Depth range (IODE standard depths): -3000.0, -2500.0, -2000.0, -1750, -1500.0, -1400.0, -1300.0, -1200.0, -1100.0, -1000.0, -900.0, -800.0, -700.0, -600.0, -500.0, -400.0, -300.0, -250.0, -200.0, -150.0, -125.0, -100.0, -75.0, -50.0,-40.0, -30.0, -20.0, -10.0, -5.0, -0.0 Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVA analysis: Geostatistical data analysis by DIVA (Data-Interpolating Variational Analysis) tool. GEBCO 1min topography is used for the contouring preparation. Analyzed filed masked using relative error threshold 0.3 and 0.5 DIVA settings. Signal to noise ratio and correlation length were optimized and filtered vertically and a seasonally-averaged profile was used. Background field: the data mean value is subtracted from the data. Detrending of data: no, Advection consraint applied: no. Units: umol/l

Moving 10-years analysis of dissolved_oxygen_concentration at Mediterranean Sea for each season : - winter (January-March), - spring (April-June), - summer (July-September), - autumn (October-December). Every year of the time dimension corresponds to the 10-year centered average of each season. Decades span from 1971-1980 until 2006-2015. Observational data span from 1911 to 2015. Depth range (IODE standard depths):-3000.0, -2500.0, -2000.0, -1750.0, -1500.0, -1400.0, -1300.0, -1200.0, -1100.0, -1000.0, -900.0, -800.0, -700.0, -600.0, -500.0, -400.0, -300.0, -250.0, -200.0, -150.0, -125.0, -100.0, -75.0, -50.0, -30.0, -20.0, -10.0, -5.0, -0.0. Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVA analysis: Geostatistical data analysis by DIVA (Data-Interpolating Variational Analysis) tool. Profiles were interpolated at standard depths using weighted parabolic interpolation algorithm (Reiniger and Ross, 1968). GEBCO 1min topography is used for the contouring preparation. Analyzed filed masked using relative error threshold 0.3 and 0.5. DIVA settings: A constant value for signal-to-noise ratio was used equal to 1. Correlation length was optimized and filtered vertically and a seasonally-averaged profile was used. Logarithmic transformation applied to the data prior to the analysis. Background field: the data mean value is subtracted from the data. Detrending of data: no. Advection constraint applied: no. Originators of Italian data sets-List of contributors: o Brunetti Fabio (OGS) o Cardin Vanessa, Bensi Manuel doi:10.6092/36728450-4296-4e6a-967d-d5b6da55f306 o Cardin Vanessa, Bensi Manuel, Ursella Laura, Siena Giuseppe doi:10.6092/f8e6d18e-f877-4aa5-a983-a03b06ccb987 o Cataletto Bruno (OGS) o Cinzia Comici Cinzia (OGS) o Civitarese Giuseppe (OGS) o DeVittor Cinzia (OGS) o Giani Michele (OGS) o Kovacevic Vedrana (OGS) o Mosetti Renzo (OGS) o Solidoro C.,Beran A.,Cataletto B.,Celussi M.,Cibic T.,Comici C.,Del Negro P.,De Vittor C.,Minocci M.,Monti M.,Fabbro C.,Falconi C.,Franzo A.,Libralato S.,Lipizer M.,Negussanti J.S.,Russel H.,Valli G., doi:10.6092/e5518899-b914-43b0-8139-023718aa63f5 o Celio Massimo (ARPA FVG) o Malaguti Antonella (ENEA) o Fonda Umani Serena (UNITS) o Bignami Francesco (ISAC/CNR) o Boldrini Alfredo (ISMAR/CNR) o Marini Mauro (ISMAR/CNR) o Miserocchi Stefano (ISMAR/CNR) o Zaccone Renata (IAMC/CNR) o Lavezza, R., Dubroca, L. F. C., Ludicone, D., Kress, N., Herut, B., Civitarese, G., Cruzado, A., Lefèvre, D., Souvermezoglou, E., Yilmaz, A., Tugrul, S., and Ribera d'Alcala, M.: Compilation of quality controlled nutrient profiles from the Mediterranean Sea, doi:10.1594/PANGAEA.771907, 2011. Units: umol/l

EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, ocean acidification, contaminants and litter. The chosen parameters are relevant for the Marine Strategy Framework Directive (MSFD), in particular for descriptors 5, 8, 9 and 10. The dataset contains standardized, harmonized and validated data collections from beach litter (monitoring and other sources). Datasets concerning beach and seafloor litter data are loaded in a central database after a semi-automated validation phase. Once loaded, a data assessment is performed in order to check data consistency and potential errors are corrected thanks to a feedback loop with data originators. For beach litter, the harmonized datasets contain all unrestricted or SeaDataNet License EMODnet Chemistry data on beach litter data, including 12390 CDI records, in which 11152 refer to monitoring data, 1208 to data from cleaning surveys and 29 to data from research. A relevant part of the monitoring data has been considered for assessment purposes by the European institutions and therefore is tagged as MSFD_monitoring. The temporal range for monitoring data is from 2001-01-01 to 2020-08-26 and includes data from 582 beaches. For data from cleaning, the temporal range is from 2013-03-12 to 2020-04-22 and includes data from 831 beaches. For data from research, the temporal range is from 2014-04-07 to 2016-10-12 and includes data from 21 beaches. EMODnet beach litter data and databases are hosted and maintained by 'Istituto Nazionale di Oceanografia e di Geofisica Sperimentale, Division of Oceanography (OGS/NODC)' from Italy. Data are formatted following Guidelines and forms for gathering marine litter data, which can be found at: https://www.emodnet-chemistry.eu/about/documents. The updated vocabularies of admitted values are available in https://www.emodnet-chemistry.eu/marinelitter/vocab. The harmonized datasets can be downloaded as EMODnet Beach litter data format Version 1.0, which is a spreadsheet file composed of 4 sheets: beach metadata, survey metadata, animals and litter. The original datasets can be searched and downloaded from EMODnet Chemistry Download Service: https://emodnet-chemistry.maris.nl/search

Combined product of Water body ammonium based on DIVA 4D 10-year analysis on five regions : Northeast Atlantic Ocean, North Sea, Baltic Sea, Black Sea, Mediterranean Sea. The boundaries and overlapping zones between these five regions were filtered to avoid any unrealistic spatial discontinuities. This combined Water body ammonium product is masked using the relative error threshold 0.5. Units: umol/l.