Moving 10-years analysis of nitrite at Mediterranean Sea for each season : - winter (January-March), - spring (April-June), - summer (July-September), - autumn (October-December). Every year of the time dimension corresponds to the 10-year centered average of each season. Decades span from 1965-1974 until 2004-2013. Observational data span from 1961 to 2013. Depth range (IODE standard depths): -1500.0, -1400.0, -1300.0, -1200.0, -1100.0, -1000.0, -900.0, -800.0, -700.0, -600.0, -500.0, -400.0, -300.0, -250.0, -200.0, -150.0, -125.0, -100.0, -75.0, -50.0, -30.0, -20.0, -10.0, -5.0, -0.0. Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVA analysis: Geostatistical data analysis by DIVA (Data-Interpolating Variational Analysis) tool. Profiles were interpolated at standard depths using weighted parabolic interpolation algorithm (Reiniger and Ross, 1968). GEBCO 1min topography is used for the contouring preparation. Analyzed filed masked using relative error threshold 0.3 and 0.5. DIVA settings: A constant value for signal-to-noise ratio was used equal to 3. Correlation length was optimized and filtered vertically and a seasonally-averaged profile was used. Logarithmic transformation applied to the data prior to the analysis. Background field: the data mean value is subtracted from the data. Detrending of data: no. Advection constraint applied: no. Originators of Italian data sets-List of contributors: o Brunetti Fabio (OGS) o Cardin Vanessa, Bensi Manuel doi:10.6092/36728450-4296-4e6a-967d-d5b6da55f306 o Cardin Vanessa, Bensi Manuel, Ursella Laura, Siena Giuseppe doi:10.6092/f8e6d18e-f877-4aa5-a983-a03b06ccb987 o Cataletto Bruno (OGS) o Cinzia Comici Cinzia (OGS) o Civitarese Giuseppe (OGS) o DeVittor Cinzia (OGS) o Giani Michele (OGS) o Kovacevic Vedrana (OGS) o Mosetti Renzo (OGS) o Solidoro C.,Beran A.,Cataletto B.,Celussi M.,Cibic T.,Comici C.,Del Negro P.,De Vittor C.,Minocci M.,Monti M.,Fabbro C.,Falconi C.,Franzo A.,Libralato S.,Lipizer M.,Negussanti J.S.,Russel H.,Valli G., doi:10.6092/e5518899-b914-43b0-8139-023718aa63f5 o Celio Massimo (ARPA FVG) o Malaguti Antonella (ENEA) o Fonda Umani Serena (UNITS) o Bignami Francesco (ISAC/CNR) o Boldrini Alfredo (ISMAR/CNR) o Marini Mauro (ISMAR/CNR) o Miserocchi Stefano (ISMAR/CNR) o Zaccone Renata (IAMC/CNR) o Lavezza, R., Dubroca, L. F. C., Ludicone, D., Kress, N., Herut, B., Civitarese, G., Cruzado, A., Lefèvre, D., Souvermezoglou, E., Yilmaz, A., Tugrul, S., and Ribera d'Alcala, M.: Compilation of quality controlled nutrient profiles from the Mediterranean Sea, doi:10.1594/PANGAEA.771907, 2011.

EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, ocean acidification and contaminants. The chemicals chosen reflect importance to the Marine Strategy Framework Directive (MSFD). This regional aggregated dataset contains all unrestricted EMODnet Chemistry data on contaminants (24 parameters), and covers the Mediterranean Sea with 4517 CDI records divided per matrices: 520 biota profiles, 560 water profiles, 3437 sediment (26 Vertical profiles and 3411 Time series). In the water dataset, the vertical profiles temporal range is from 1974-09-12 to 2015-09-14. In sediment dataset, vertical profiles temporal range is from 2010-08-02 to 2014-09-28 and time series temporal range is from 1981-06-27 to 2018-08-02. In biota time series temporal range is from 1979-03-29 to 2017-03-15. Data were aggregated and quality controlled by ‘Hellenic Centre for Marine Research, Hellenic National Oceanographic Data Centre (HCMR/HNODC)’ from Greece. Regional datasets concerning contaminants are automatically harvested. Parameter names in these datasets are based on P01, BODC Parameter Usage Vocabulary, which is available at: http://seadatanet.maris2.nl/bandit/browse_step.php . Each measurement value has a quality flag indicator. The resulting data collections for each Sea Basin are harmonised, and the collections are quality controlled by EMODnet Chemistry Regional Leaders using ODV Software and following a common methodology for all Sea Regions. Harmonisation means that: (1) unit conversion is carried out to express contaminant concentrations with a limited set of measurement units (according to EU directives 2013/39/UE; Comm. Dec. EU 2017/848) and (2) merging of variables described by different “local names” ,but corresponding exactly to the same concepts in BODC P01 vocabulary. The harmonised dataset can be downloaded as ODV spreadsheet (TXT file), which is composed of metadata header followed by tab separated values. This worksheet can be imported to ODV Software for visualisation (More information can be found at: https://www.seadatanet.org/Software/ODV ). The same dataset is offered also as XLSX file in a long/vertical format, in which each P01 measurement is a record line. Additionally, there are a series of columns that split P01 terms in subcomponents (measure, substance, CAS number, matrix...).This transposed format is more adapted to worksheet applications users (e.g. LibreOffice Calc). The 24 parameter names in this metadata record are based on P02, SeaDataNet Parameter Discovery Vocabulary, which is available at: http://seadatanet.maris2.nl/v_bodc_vocab_v2/vocab_relations.asp?lib=P02 . Detailed documentation will be published soon. The original datasets can be searched and downloaded from EMODnet Chemistry Download Service: https://emodnet-chemistry.maris.nl/search

Moving 10-years analysis of ammonium at Mediterranean Sea for each season : - winter (January-March), - spring (April-June), - summer (July-September), - autumn (October-December). Every year of the time dimension corresponds to the 10-year centered average of the winter season. Decades span from 1977-1986 until 2004-2013. Observational data span from 1970 to 2013. Depth range (IODE standard depths): -1000.0, -900.0, -800.0, -700.0, -600.0, -500.0, -400.0, -300.0, -250.0, -200.0, -150.0, -125.0, -100.0, -75.0, -50.0, -30.0, -20.0, -10.0, -5.0, -0.0. Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVA analysis: Geostatistical data analysis by DIVA (Data-Interpolating Variational Analysis) tool. Profiles were interpolated at standard depths using weighted parabolic interpolation algorithm (Reiniger and Ross, 1968). GEBCO 1min topography is used for the contouring preparation. Analyzed filed masked using relative error threshold 0.3 and 0.5. DIVA settings: A constant value for signal-to-noise ratio was used equal to 3. Correlation length was optimized and filtered vertically and a seasonally-averaged profile was used. Logarithmic transformation applied to the data prior to the analysis. Background field: the data mean value is subtracted from the data. Detrending of data: no. Advection constraint applied: no. Originators of Italian data sets-List of contributors: o Brunetti Fabio (OGS) o Cardin Vanessa, Bensi Manuel doi:10.6092/36728450-4296-4e6a-967d-d5b6da55f306 o Cardin Vanessa, Bensi Manuel, Ursella Laura, Siena Giuseppe doi:10.6092/f8e6d18e-f877-4aa5-a983-a03b06ccb987 o Cataletto Bruno (OGS) o Cinzia Comici Cinzia (OGS) o Civitarese Giuseppe (OGS) o DeVittor Cinzia (OGS) o Giani Michele (OGS) o Kovacevic Vedrana (OGS) o Mosetti Renzo (OGS) o Solidoro C.,Beran A.,Cataletto B.,Celussi M.,Cibic T.,Comici C.,Del Negro P.,De Vittor C.,Minocci M.,Monti M.,Fabbro C.,Falconi C.,Franzo A.,Libralato S.,Lipizer M.,Negussanti J.S.,Russel H.,Valli G., doi:10.6092/e5518899-b914-43b0-8139-023718aa63f5 o Celio Massimo (ARPA FVG) o Malaguti Antonella (ENEA) o Fonda Umani Serena (UNITS) o Bignami Francesco (ISAC/CNR) o Boldrini Alfredo (ISMAR/CNR) o Marini Mauro (ISMAR/CNR) o Miserocchi Stefano (ISMAR/CNR) o Zaccone Renata (IAMC/CNR) o Lavezza, R., Dubroca, L. F. C., Ludicone, D., Kress, N., Herut, B., Civitarese, G., Cruzado, A., Lefèvre, D., Souvermezoglou, E., Yilmaz, A., Tugrul, S., and Ribera d'Alcala, M.: Compilation of quality controlled nutrient profiles from the Mediterranean Sea, doi:10.1594/PANGAEA.771907, 2011.

Moving 10-years analysis of nitrates at Mediterranean Sea for each season : - winter (January-March), - spring (April-June), - summer (July-September), - autumn (October-December). Every year of the time dimension corresponds to the 10-year centered average of each season. Decades span from 1960-1969 until 2004-2013. Observational data span from 1960 to 2013. Depth range (IODE standard depths): -1500.0, -1400.0, -1300.0, -1200.0, -1100.0, -1000.0, -900.0, -800.0, -700.0, -600.0, -500.0, -400.0, -300.0, -250.0, -200.0, -150.0, -125.0, -100.0, -75.0, -50.0, -30.0, -20.0, -10.0, -5.0, -0.0. Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVA analysis: Geostatistical data analysis by DIVA (Data-Interpolating Variational Analysis) tool. Profiles were interpolated at standard depths using weighted parabolic interpolation algorithm (Reiniger and Ross, 1968). GEBCO 1min topography is used for the contouring preparation. Analyzed filed masked using relative error threshold 0.3 and 0.5. DIVA settings: A constant value for signal-to-noise ratio was used equal to 3. Correlation length was optimized and filtered vertically and a seasonally-averaged profile was used. Logarithmic transformation applied to the data prior to the analysis. Background field: the data mean value is subtracted from the data. Detrending of data: no. Advection constraint applied: no. Originators of Italian data sets-List of contributors • Brunetti Fabio (OGS) • Cardin Vanessa, Bensi Manuel doi:10.6092/36728450-4296-4e6a-967d-d5b6da55f306 • Cardin Vanessa, Bensi Manuel, Ursella Laura, Siena Giuseppe doi:10.6092/f8e6d18e-f877-4aa5-a983-a03b06ccb987 • Cataletto Bruno (OGS) • Cinzia Comici Cinzia (OGS) • Civitarese Giuseppe (OGS) • DeVittor Cinzia (OGS) • Giani Michele (OGS) • Kovacevic Vedrana (OGS) • Mosetti Renzo (OGS) • Solidoro C.,Beran A.,Cataletto B.,Celussi M.,Cibic T.,Comici C.,Del Negro P.,De Vittor C.,Minocci M.,Monti M.,Fabbro C.,Falconi C.,Franzo A.,Libralato S.,Lipizer M.,Negussanti J.S.,Russel H.,Valli G., doi:10.6092/e5518899-b914-43b0-8139-023718aa63f5 • Celio Massimo (ARPA FVG) • Malaguti Antonella (ENEA) • Fonda Umani Serena (UNITS) • Bignami Francesco (ISAC/CNR) • Boldrini Alfredo (ISMAR/CNR) • Marini Mauro (ISMAR/CNR) • Miserocchi Stefano (ISMAR/CNR) • Zaccone Renata (IAMC/CNR) • Lavezza, R., Dubroca, L. F. C., Ludicone, D., Kress, N., Herut, B., Civitarese, G., Cruzado, A., Lefèvre, D., Souvermezoglou, E., Yilmaz, A., Tugrul, S., and Ribera d’Alcala, M.: Compilation of quality controlled nutrient profiles from the Mediterranean Sea, doi:10.1594/PANGAEA.771907, 2011. Units: umol/l

Water body silicate - Seasonal Climatology for Po River for the period 1980-2019 on the domain: Lon E12.0-14.0 deg.E, Lat N44.0-46.00 deg.N. Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVA analysis: The computation was done with the DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.4, using GEBCO 30sec topography for the spatial connectivity of water masses. A relative correlation length used based on topography gradients and the horizontal correlation length varies from 25 km to 12.5 km. The vertical correlation length (in meters) is: [4.,4.,4.,4.,4.,10.,10.,10.,10.,20.,20.,20.,20.,20.]. Depth range: [0., 2., 4., 6., 8., 10., 15., 20., 25., 30., 40., 50., 60., 70.]. Units: umol/l. The horizontal resolution of the produced DIVAnd maps grids is dx=dy=0.009 degrees (around 975m and 708m accordingly). Additional analysis parameters: The error variance (epsilon2) was set equal to 1. Data weight was reduced near the coasts. Data weighting was applied with the following threshold values: lon=0.03, lat=0.03, depth=2. Threshold value for log transformation=200. Seasons definition: Winter=Jan-Mar, Spring=Apr-Jun, Summer=Jul-Sep, Autumn=Oct-Dec. DOI: 10.6092/njvc-n987

Dissolved inorganic nitrogen (DIN) - Seasonal Climatology for Po River for the period 1980-2019 on the domain: Lon E12.0-14.0 deg.E, Lat N44.0-46.00 deg.N. Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVA analysis: The computation was done with the DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.4, using GEBCO 30sec topography for the spatial connectivity of water masses. A relative correlation length used based on topography gradients and the horizontal correlation length varies from 25 km to 12.5 km. The vertical correlation length (in meters) is: [4.,4.,4.,4.,4.,10.,10.,10.,10.,20.,20.,20.,20.,20.]. Depth range: [0., 2., 4., 6., 8., 10., 15., 20., 25., 30., 40., 50., 60., 70.]. Units: umol/l. The horizontal resolution of the produced DIVAnd maps grids is dx=dy=0.009 degrees (around 975m and 708m accordingly). Additional analysis parameters: The error variance (epsilon2) was set equal to 1. Data weight was reduced near the coasts. Data weighting was applied with the following threshold values: lon=0.03, lat=0.03, depth=2. Threshold value for log transformation=200. Seasons definition: Winter=Jan-Mar, Spring=Apr-Jun, Summer=Jul-Sep, Autumn=Oct-Dec. DOI: 10.6092/p8ec-3v81

Water body phosphate - Seasonal Climatology for Po River for the period 1980-2019 on the domain: Lon E12.0-14.0 deg.E, Lat N44.0-46.00 deg.N. Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVA analysis: The computation was done with the DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.4, using GEBCO 30sec topography for the spatial connectivity of water masses. A relative correlation length used based on topography gradients and the horizontal correlation length varies from 25 km to 12.5 km. The vertical correlation length (in meters) is: [4.,4.,4.,4.,4.,10.,10.,10.,10.,20.,20.,20.,20.,20.]. Depth range: [0., 2., 4., 6., 8., 10., 15., 20., 25., 30., 40., 50., 60., 70.]. Units: umol/l. The horizontal resolution of the produced DIVAnd maps grids is dx=dy=0.009 degrees (around 975m and 708m accordingly). Additional analysis parameters: The error variance (epsilon2) was set equal to 1. Data weight was reduced near the coasts. Data weighting was applied with the following threshold values: lon=0.03, lat=0.03, depth=2. Threshold value for log transformation=200. Seasons definition: Winter=Jan-Mar, Spring=Apr-Jun, Summer=Jul-Sep, Autumn=Oct-Dec. DOI: 10.6092/jb28-9k33

Water body chlorophyll-a - Seasonal Climatology for Po River for the period 1980-2019 on the domain: Lon E12.0-14.0 deg.E, Lat N44.0-46.00 deg.N. Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVA analysis: The computation was done with the DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.4, using GEBCO 30sec topography for the spatial connectivity of water masses. A relative correlation length used based on topography gradients and the horizontal correlation length varies from 25 km to 12.5 km. The vertical correlation length (in meters) is: [4.,4.,4.,4.,4.,10.,10.,10.,10.,20.,20.,20.,20.,20.]. Depth range: [0., 2., 4., 6., 8., 10., 15., 20., 25., 30., 40., 50., 60., 70.]. Units: mg/m3. The horizontal resolution of the produced DIVAnd maps grids is dx=dy=0.009 degrees (around 975m and 708m accordingly). Additional analysis parameters: The error variance (epsilon2) was set equal to 1. Data weight was reduced near the coasts. Data weighting was applied with the following threshold values: lon=0.03, lat=0.03, depth=2. Threshold value for log transformation=200. Seasons definition: Winter=Jan-Mar, Spring=Apr-Jun, Summer=Jul-Sep, Autumn=Oct-Dec. DOI: 10.6092/nv0n-4996

Water body dissolved oxygen concentration - Seasonal Climatology for Po River for the period 1960-2019 on the domain: Lon E12.0-14.0 deg.E, Lat N44.0-46.00 deg.N. Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVA analysis: The computation was done with the DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.4, using GEBCO 30sec topography for the spatial connectivity of water masses. A relative correlation length used based on topography gradients and the horizontal correlation length varies from 25 km to 12.5 km. The vertical correlation length (in meters) is: [4.,4.,4.,4.,4.,10.,10.,10.,10.,20.,20.,20.,20.,20.]. Depth range: [0., 2., 4., 6., 8., 10., 15., 20., 25., 30., 40., 50., 60., 70.]. Units: umol/l. The horizontal resolution of the produced DIVAnd maps grids is dx=dy=0.009 degrees (around 975m and 708m accordingly). Additional analysis parameters: The error variance (epsilon2) was set equal to 1. Data weight was reduced near the coasts. Data weighting was applied with the following threshold values: lon=0.03, lat=0.03, depth=2. Threshold value for log transformation=200. Seasons definition: Winter=Jan-Mar, Spring=Apr-Jun, Summer=Jul-Sep, Autumn=Oct-Dec. DOI: 10.6092/tasv-9066

Gridded product for visualization of Water body phosphate in the Black Sea generated by DIVA 4.6.9 using all EMODNET Chemistry data from 1960 to 2013. Depth range (IODE standard depths): 0 – 200m. DIVA settings: signal-to-noise ratio and correlation length were estimated using data mean distance as a minimum (for L), and both parameters vertically filtered. Background field: the data mean value is subtracted from the data. Detrending of data: no. Advection constraint applied: no. Every year of the time dimension corresponds to a 10-year centred average for each season: - winter: December - February, - spring: March - May, - summer: June - August, - autumn: September – November Units: umol/l